Acids and bases
DETAIL
and hydroxide anions OH−
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Sodium hydroxide is a highly caustic base and alkali that decomposes proteins at ordinary ambient temperatures and may cause severe chemical burns. It is highly soluble in water, and readily absorbs moisture and carbon dioxide from the air.
Sodium hydroxide is used in many industries: in the manufacture of pulp and paper, textiles, drinking water, soaps and detergents, and as a drain cleaner.
Production
Sodium hydroxide is industrially produced as a 50% solution by variations of the electrolytic chloralkali process. Chlorine gas is also produced in this process. Solid sodium hydroxide is obtained from this solution by the evaporation of water. Solid sodium hydroxide is most commonly sold as flakes, prills, and cast blocks.
Uses
See also: Hydrodesulfurization
Sodium hydroxide is a popular strong base used in industry. Sodium hydroxide is used in the manufacture of sodium salts and detergents, pH regulation, and organic synthesis. In bulk, it is most often handled as an aqueous solution, since solutions are cheaper and easier to handle.
Sodium hydroxide is used in many scenarios where it is desirable to increase the alkalinity of a mixture, or to neutralize acids.
For example, in the petroleum industry, sodium hydroxide is used as an additive in drilling mud to increase alkalinity in bentonite mud systems, to increase the mud viscosity, and to neutralize any acid gas (such as hydrogen sulfide and carbon dioxide) which may be encountered in the geological formation as drilling progresses.
Another use is in Salt spray testing where pH needs to be regulated. Sodium hydroxide is used with hydrochloric acid to balance pH. The resultant salt, NaCl, is the corrosive agent used in the standard neutral pH salt spray test.
Other common uses of sodium hydroxide include:
It is used for making soaps and detergents. Sodium hydroxide is used for hard bar soap while potassium hydroxide is used for liquid soaps.sodium hydroxide is used more often than potassium hydroxide because it is cheaper and a smaller quantity is needed.
It is used as drain cleaners that contain sodium hydroxide convert fats and grease that can clog pipes into soap, which dissolves in water. (see cleaning agent)
It is used for making artificial textile fibres (such as Rayon).
It is used in the manufacture of paper. Around 56% of sodium hydroxide produced is used by industry, 25% of which is used in the paper industry. (see chemical pulping)
It is used in purifying bauxite ore from which aluminium metal is extracted. This is known as Bayer process. (see dissolving amphoteric metals and compounds)
It is used in de-greasing metals, oil refining, and making dyes and bleaches.
It is used in water treatment plants for pH regulation.
It is used to treat bagels and pretzel dough, giving the distinctive shiny finish.
Chemical pulping
Main article: Pulp (paper)
Sodium hydroxide is also widely used in pulping of wood for making paper or regenerated fibers. Along with sodium sulfide, sodium hydroxide is a key component of the white liquor solution used to separate lignin from cellulose fibers in the kraft process.
Cleaning agent
Main article: Cleaning agent
Sodium hydroxide is frequently used as an industrial cleaning agent where it is often called "caustic". It is added to water, heated, and then used to clean process equipment, storage tanks, etc. It can dissolve grease, oils, fats and protein-based deposits. It is also used for cleaning waste discharge pipes under sinks and drains in domestic properties. Surfactants can be added to the sodium hydroxide solution in order to stabilize dissolved substances and thus prevent redeposition. A sodium hydroxide soak solution is used as a powerful degreaser on stainless steel and glass bakeware. It is also a common ingredient in oven cleaners.
A common use of sodium hydroxide is in the production of parts washer detergents. Parts washer detergents based on sodium hydroxide are some of the most aggressive parts washer cleaning chemicals. The sodium hydroxide-based detergents include surfactants, rust inhibitors and defoamers. A parts washer heats water and the detergent in a closed cabinet and then sprays the heated sodium hydroxide and hot water at pressure against dirty parts for degreasing applications. Sodium hydroxide used in this manner replaced many solvent-based systems in the early 1990s[citation needed] when trichloroethane was outlawed by the Montreal Protocol. Water and sodium hydroxide detergent-based parts washers are considered to be an environmental improvement over the solvent-based cleaning methods.
Water treatment
Sodium hydroxide is sometimes used during water purification to raise the pH of water supplies. Increased pH makes the water less corrosive to plumbing and reduces the amount of lead, copper and other toxic metals that can dissolve into drinking water.